I have had several twin cam heads off in my days of wrenching. Most of them DSM heads. Even with the cams disconnected via a broken belt, you cannot set it up somewhere so that NO valves are open at least part way.
remember we are not talking about one cylinder here but all 4. Each cam works 8 valves so at least 2 will be open.
Now, even if by some fluke when the belt broke, the engine stopped in such a way as to have one piston down and only 2 of that cylinders valves open, you cranked it to try to restart it. Just like any one of us would have. Now, there there is no way all the valves are still good. If those valves were closed, and the piston was down, when you cranked it, the valves did not move because the cam cannot turn due to no belt on it. The piston however did move, assuming the crank and rod are still good.
Assuming all is stock or stock replacement inside that engine(no aftermarket pistons with larger valve reliefs cut in them, no really strong stainless alloy valves, no real thick spacer head gasket), some valves are bent. Probably 4 or 8. Some won't be badly bent, but won't seal to the seat.
Even if it looks good, I strongly suggest you send the head to a competant machine shop so that they can test it to see if the valves seal. They seal each chamber and pull a vacuum on it. If they don't seal, its obvious, but not visible some times. I'd hate to see you go to all that trouble and then have to do it again, plus another head gasket, set of bolts, oil, coolant etc.
Hey, I wish you luck, it would be really great for you if we were all wrong, but the chances are VERY minute.